4.7 Article

Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 68, Pages 7501-7503

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43723j

Keywords

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Funding

  1. National Natural Science Foundation of China [21172185]
  2. Hunan Provincial Natural Science Foundation of China [11JJ1003, 12JJ7002]
  3. New Century Excellent Talents in University from Ministry of Education of China [NCET-11-0974]
  4. Hunan Provincial Innovative Foundation for Postgraduate [CX2012B250]

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A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions.

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