4.7 Article

A three-dimensional pi-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 82, Pages 9398-9400

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45313h

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Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science and Technology [NRF-2011-0013481]
  3. Industrial strategic technology development program [10041556]
  4. Ministry of Knowledge Economy (MKE)

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Electron accepting capability is greatly improved for B-phenylated tri-phenyl-o-carborane (1) through a favorable electronic interaction between the two adjoining phenyl-pi(star) and cage carbon-sigma(star) orbitals.

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