4.7 Article

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 65, Pages 7249-7251

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42695e

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Funding

  1. Japanese government [23750174]
  2. GCOE program Education and Research Center for Emergence of New Molecular Chemistry''

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Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.

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