Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 57, Pages 6442-6444Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42686f
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Funding
- NSFC [21102081, 21272133]
- New Teachers' Fund for Doctor Stations Ministry of Education [20110002120011]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education [20121027968]
- Beijing Natural Science Foundation [2132037]
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The first total syntheses of spirobacillenes A and B were achieved concisely. The key transformation leading to spirobacillene A features a biomimetic intramolecular phenol-enol oxidative coupling reaction, and that leading to spirobacillene B highlights a bio-inspired intramolecular indole-ketone enolate oxidative coupling reaction.
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