Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 9, Pages 928-930Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc38097h
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Funding
- National Science foundation [CHE-1057569]
- China 111 Project [B07023]
- East China University of Science Technology
- NSF [0840523, 0946690]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1057569] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0946690, 0840523] Funding Source: National Science Foundation
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An organocatalytic enantioselective addition reaction of cyclic ketoimines with phosphites has been developed for the first time. The process, catalyzed by Soos' quinine thiourea, affords synthetically and medicinally interesting enantioenriched trifluoromethyl dihydroquinazolinones in high yields and with high enantioselectivities.
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