4.7 Article

A bowl-shaped organic host using bispyridine ligands: selective encapsulation of carbonyl guests in water

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 16, Pages 1630-1632

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38869g

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Funding

  1. JSPS
  2. Grants-in-Aid for Scientific Research [12J04743] Funding Source: KAKEN

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A bowl-shaped organic host was prepared by linking two anthracene-embedded bispyridine ligands with two methylene spacers. The water-soluble host has a hemispherical hydrophobic cavity (similar to 1 nm in diameter) with two cationic methylenebispyridinyl (Lewis acidic) moieties and shows the selective recognition and encapsulation of aromatic guest molecules containing carbonyl groups in water.

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