Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 90, Pages 10575-10577Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46398b
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Funding
- Dutch National Research School Combination Catalysis Controlled by Chemical Design (NRSC-Catalysis)
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NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.
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