Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 58, Pages 6516-6518Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43597k
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Funding
- NIH [GM31278]
- Robert A. Welch Foundation [GL625910]
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We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N-CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.
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