Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 61, Pages 6894-6896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43359e
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Funding
- DHS [2009-ST-108-LR0005]
- NSF [CAREER CHE 0641353]
- DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Department of Chemistry and Biochemistry, SIUC
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0931466] Funding Source: National Science Foundation
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A water soluble perylene diimide molecule has been fabricated into nanofibers via a pH triggered hydrogelation route. The one-dimensional self-assembly is dominated by the intermolecular pi-pi stacking interactions in concert with the hydrogen bonding between the carboxylic acid side chains. The anisotropic electronic and optical properties observed for the nanofibers are consistent with the one-dimensional intermolecular pi-pi arrangement.
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