4.7 Article

A carbon-nanotube-supported graphene-rich non-precious metal oxygen reduction catalyst with enhanced performance durability

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 32, Pages 3291-3293

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc39121c

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Funding

  1. U.S. DOE's Fuel Cell Technologies Program
  2. LANL Laboratory-Directed Research and Development Programs
  3. Office of Science
  4. Office of Basic Energy Sciences
  5. ORNL's ShaRE User Facility
  6. Office of Basic Energy Sciences, U.S. DOE

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A non-precious metal catalyst for oxygen reduction in acid media, enriched in graphene sheets/bubbles during a high-temperature synthesis step, has been developed from an Fe precursor and in situ polymerized polyaniline, supported on multi-walled carbon nanotubes. The catalyst showed no performance loss for 500 hours in a hydrogen/air fuel cell. The improved durability is correlated with the graphene formation, apparently enhanced in the presence of carbon nanotubes.

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