4.7 Article

Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 99, Pages 11686-11688

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45960h

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Funding

  1. 973 project of China [2009CB930403, 2013CB934101]
  2. Evonik Industries
  3. [25390023]

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Chiral metal oxide complexes with tunable optical response to circularly polarised light over the full range of the UV-Vis absorption band were synthesised. This optical activity was attributed to electronic transitions from the ground state to the excited state or from the valence band to the conduction band under an asymmetric electric field.

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