4.7 Article

Cucurbit[8]uril-based supramolecular polymers: promoting supramolecular polymerization by metal-coordination

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 51, Pages 5766-5768

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41864b

Keywords

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Funding

  1. National Basic Research Program of China [2013CB834502]
  2. NSFC Innovative Group [21121004]
  3. NSFC [21274076]
  4. NSFC-DFG [TRR61]

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Linear supramolecular polymers were obtained in aqueous solution by employing cucurbit[8]uril-based host-guest interaction as the driving force. Water-soluble monomers were prepared through direct metal-coordination. The rigid and bulky terpyridine-Fe linker can effectively enhance the monomer's solubility and suppress its cyclization, thereby promoting supramolecular polymerization.

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