4.7 Article

Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 17, Pages 1732-1734

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38287g

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Funding

  1. NSERC (Canada)
  2. Spanish Ministry of Economy and Competitiveness [CTQ2011-27758]
  3. Marie Curie Career Integration Grant within the 7th European Community Framework Programme

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Surface plasmon excitation of gold nanoparticles on ZnO in the presence of an aldehyde, an amine and phenylacetylene led to rapid and selective formation of propargylamines with good yields (50-95%) at room temperature. Plasmon mediated catalysis is the best available route for this ternary coupling.

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