Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 33, Pages 3416-3418Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc00152k
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The performance of well-defined ultrasmall iron(0) nanoparticles (NPs) as catalysts for the selective hydrogenation of unsaturated C-C and C=X bonds is reported. Monodisperse iron nanoparticles of about 2 nm size are synthesized by the decomposition of {Fe(N[Si(CH3)(3)](2))(2)}(2) under dihydrogen. They are found to be active for the hydrogenation of various alkenes and alkynes under mild conditions and weakly active for C=O bond hydrogenation.
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