Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 3, Pages 300-302Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37347e
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Funding
- MOST of China [2011CB932403]
- NSFC [21131005, 21021061, 20925103, 20871100]
- Fok Ying Tung Education Foundation [121011]
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A yellow luminescent thiolate-protected Ag-14(SC6H3F2)(12)(PPh3)(8) cluster was synthesized and structurally characterized by single-crystal X-ray analysis. The cluster contains an octahedral Ag-6(4+) unit encapsulated by eight cubically arranged [Ag+(SC6H3F2-)(2)PPh3] tetrahedra that share one corner (i.e. SC6H3F2-) between them.
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