Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 22, Pages 2183-2185Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38841g
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
- Russian Foundation for Basic Research (RFBR)
- Landesstiftung Baden-Wurttemberg GmbH
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The two new 3d/4f polyphosphide complexes [(Cp*Fe)(2)P-10{Sm-(eta(5)-C5Me4R)(2)}(2)] (Cp* = eta 5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(eta(5)-P-5)] with samarocenes. They are the first P-10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.
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