4.7 Article

A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 72, Pages 7950-7952

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43637c

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Funding

  1. National Science Foundation [CHE 1214109]
  2. Industry/University Cooperative Research Center for Fundamentals and Applications of Photopolymerizations
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1214109] Funding Source: National Science Foundation

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A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

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