4.7 Article

Nickel-catalyzed decyanation of inert carbon-cyano bonds

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 1, Pages 69-71

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36883h

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Funding

  1. BRNS, India [2011/20/37C/13/BRNS]
  2. UGC-India
  3. IIT Bombay

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Nickel catalyzed decyanation of aryl and aliphatic cyanides with hydrosilane as the hydride source has been developed. This method is easy to handle, scalable and can be carried out without a glove box. The method has been applied in the cyanide directed functionalization reaction and alpha-substitution of benzyl cyanide.

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