4.7 Article

A dinuclear alkynylplatinum(II) pyridinedicarboxamide: conformational change-induced switching of emission properties

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 12, Pages 1163-1165

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37706c

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Funding

  1. JSPS
  2. Ministry of Education, Culture, Sports, Science and Technology, Japan
  3. Grants-in-Aid for Scientific Research [24108722] Funding Source: KAKEN

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The synthesis and characterisation of a dinuclear pyridinedicarbox-amide-platinum(II) complex exhibiting tunable optical properties based on metal-metal interaction are reported. Conformational change-induced switching between metal-to-ligand charge-transfer and metal-metal-to-ligand charge-transfer emission properties by the influence of methanol was demonstrated.

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