4.7 Article

Direct access to triazole-olefins through catalytic cycloaddition of azides to unsaturated aldehydes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 86, Pages 10187-10189

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45306e

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Funding

  1. Singapore (Academic Research Grant) [R143000480112, R143000443112, NRF-CRP7-2010-03]

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In situ formed dienamines as HOMO-raising dipolarophiles react with azides to afford the corresponding triazole-olefins in good to excellent yields via a catalytic inverse-electron-demand 1,3-dipolar cycloaddition process.

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