Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 14, Pages 1419-1421Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37793d
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Funding
- U.S. Department of Energy [DE-SC0004888]
- China Scholarship Council (CSC)
- Zhejiang Provincial Natural Science Foundation of China [Y4100189]
- U.S. Department of Energy (DOE) [DE-SC0004888] Funding Source: U.S. Department of Energy (DOE)
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Flowing supercritical CO2 was used to activate a cross section of microporous coordination polymers (MCPs) directly from DMF, thus avoiding exchange with a volatile solvent. Most MCPs displayed exceptional surface areas directly after treatment although those with coordinatively unsaturated metals benefit from heating. The method presents an advance in efficiency of activation and quality of material obtained.
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