Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 68, Pages 7480-7482Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43072c
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Funding
- National Science Centre (Poland) [2011/01/B/ST5/06673]
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Divalent silver is stabilized in concentrated sulphuric acid and oleums. The formal redox potential of the Ag(II)/Ag(I) redox pair is markedly dependent on the Hammett acidity function and it reaches +2.90 V vs. NHE in 33% oleum thus rivalling E degrees for the F-2/2F(-) redox pair (+2.87 V).
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