4.7 Article

Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 82, Pages 9455-9457

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43491e

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Funding

  1. Natural Science Foundation of China [21120102036, 91233201]
  2. Basic Research Program of China [2009CB220009]
  3. K & A Wallenberg Foundation of Sweden
  4. Universite de Bretagne Occidentale
  5. Ecole Doctorale SICMA for PhD student fellowship

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A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H-2 production from neutral water, with an activity of 860 mol H-2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at-1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.

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