Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 82, Pages 9455-9457Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43491e
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Funding
- Natural Science Foundation of China [21120102036, 91233201]
- Basic Research Program of China [2009CB220009]
- K & A Wallenberg Foundation of Sweden
- Universite de Bretagne Occidentale
- Ecole Doctorale SICMA for PhD student fellowship
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A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H-2 production from neutral water, with an activity of 860 mol H-2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at-1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.
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