4.7 Article

A homoleptic tetravalent cerium silylamide

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 1, Pages 87-89

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37404h

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Funding

  1. University of Bergen
  2. Meltzer Foundation

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Treatment of Ce[N(SiHMe2)(2)](3)(thf)(2) with the chlorinating agents PhICl2, Ph3CCl or C2Cl6 gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe2)(2)](4). When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce-5[N(SiHMe2)(2)](8)Cl-7 was isolated.

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