Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 63, Pages 7055-7057Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43299h
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-FG02-09ER46650, DE-AC02-06CH11357, DE-FG02-08ER46491]
- National Science Foundation/Department of Energy [NSF/CHE-0822838]
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A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N-2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
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