4.7 Article

Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 82, Pages 9491-9493

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45823g

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Funding

  1. Shanghai Pujiang Talent Program [11PJ1402500]
  2. Fundamental Research Funds for the Central Universities [WK1114014]
  3. Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
  4. National Basic Research Program of China (973) [2010CB833302]
  5. National Natural Science Foundation of China [21171056, 21072206]

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Three ruthenium complexes bearing backbone-monosubstituted CAACs were prepared and displayed dramatic improvement in catalytic efficiency not only in RCM reaction but also in the ethenolysis of methyl oleate, compared to those bearing backbone-disubstituted CAACs.

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