4.7 Article

Controlled folding of a novel electroactive polyolefin via multiple sequential orthogonal intra-chain interactions

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 39, Pages 4178-4180

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37157j

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Funding

  1. NSF via the Nanoscale Science & Engineering Center for High-rate Nanomanufacturing [NSF EEC 0832785]
  2. University of New Hampshire

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We report here the synthesis of a novel electroactive polyolefin and demonstrate through a combination of SEC-MALS and DLS how this type of functional polymer can be folded in a controlled fashion from an expanded coil to a tightly wound globule using sequentially activated noncovalent and covalent intra-chain interactions.

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