4.7 Article

Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 26, Pages 2682-2684

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc39286d

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Funding

  1. National Natural Science Foundation of China [21171124, 21201068]
  2. 333 Project of Jiangsu Province
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions
  4. Natural Science Foundation of Anhui Province [1208085QB26]

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The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)(2)](n) produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)(0.5)](n) through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H(2)bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]center dot H2O}(n) in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.

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