Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 52, Pages 5829-5831Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43145b
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- EPSRC
- ERC (FUNCAT)
- Royal Society
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[RuCl(PPh3)(2)(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200).
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