4.7 Article

A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 66, Pages 7289-7291

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44175j

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Funding

  1. Fluid Interface Reactions, Structures, and Transport (FIRST) Center, an Energy Frontier Research Center
  2. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (Carbons, BET, CV, TEM)
  3. Division of Chemical Sciences, Geosciences, and Biosciences (ILs, NMR, MS, TEM)
  4. GMV Division of Materials Sciences and Engineering (XPS, BET)
  5. U.S. Department of Energy's Office of Basic Energy Science

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Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afforded microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.

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