Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 93, Pages 10986-10988Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46624h
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Funding
- BMBF [05ES3XBA/5]
- Marie Curie RTN [PITN-GA-2009-238804]
- [VEGA 1/0052/11]
- [APVV-0014-11]
- [APVV-0132-11]
- [SK-GR-0022-11]
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Abrupt room temperature switching (T-c = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl) pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.
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