4.7 Article

Single-molecule observation of the K+-induced switching of valinomycin within a template network

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 79, Pages 9021-9023

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44978e

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Funding

  1. National Science and Technology Ministry [2009BAI78B01, 2009BAI78B02]
  2. National Natural Science Foundation of China [21073048, 51173031, 91127043]
  3. Jiangxi Province Education Department Science Fund [GJJ13664]

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The K+-induced switching of valinomycin has been studied using a molecular template formed by an aromatic oligoamide macrocycle at the liquid/solid interface by scanning tunneling microscopy (STM). Individual valinomycin and its K+ complex can be identified and resolved in the molecular template, and the high-resolution STM images of valinomycin and its K+ complex show triangle-like and cyclic structural characteristics, respectively.

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