4.7 Article

Chemical conversion of beta-O-4 lignin linkage models through Cu-catalyzed aerobic amide bond formation

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 97, Pages 11439-11441

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46912c

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Funding

  1. Nanyang Technological University
  2. Singapore Ministry of Education [MOE2011-T2-1-013, MOE2012-T2-1-014]
  3. National Environment Agency (NEA-ETRP) [1002 111]
  4. University of Science and Technology of China

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Methods for conversion of the lignin beta-O-4 models into amide derivatives and phenols have been developed, which is achieved via chemo-selective oxidation of the secondary benzylic alcohol and subsequent Cu-catalyzed aerobic amide bond formation.

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