4.7 Article

Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 99, Pages 11623-11625

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46887a

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Funding

  1. KAIST (HRHRP)
  2. National Research Foundation of Korea [2011-0014197]
  3. Institute for Basic Science (IBS)

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Stereoselective cis-trans isomerism of a Co-III-N2O2 complex has been achieved by coordinating chiral vicinal diamines. The induced metal-centered helical chirality can be exploited for chirality amplification and asymmetric coordination chemistry.

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