Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 91, Pages 10745-10747Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47030j
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Funding
- ERC (Advanced Investigator Award-FUNCAT)
- EPSRC
- Syngenta
- Royal Society
- Uehara Memorial Foundation
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The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)((OOBu)-Bu-t)] and [Au(SIPr)((OOBu)-Bu-t)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as synthons. These complexes have been successfully used in oxygen-transfer reactions to triphenylphosphine.
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