Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 91, Pages 10666-10675Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45466e
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Funding
- Spanish Ministerio de Economia y Competitividad [CTQ2011-28512]
- Generalitat de Catalunya [2009SGR 00623]
- ICIQ Foundation
- ICREA Funding Source: Custom
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Herein an overview of reductive catalytic enantioselective desymmetrisation of achiral or meso compounds is provided. The most efficient reductive desymmetrisations described in the literature, which involve the reduction of C=O, C=N, C=C and C-halogen bonds, or reductive ring-opening, are summarised. The structural diversity of the valuable highly enantioenriched intermediates prepared by reductive desymmetrisation is highlighted.
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