Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 90, Pages 10578-10580Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45235b
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In this work, we subject bi- and terpyrenyls to selective fusion for formation of extended polycyclic aromatic hydrocarbons (PAHs). Connecting the pyrene units at 4-4'- or 1-4'-positions led to smooth formation of extended PAHs, achieved via cyclodehydrogenation. This is far more difficult if pyrene is coupled in the 1,1'-position.
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