Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 83, Pages 9669-9671Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45099f
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Funding
- National Research Foundation of Korea [NRF]
- Korea government [MSIP] [20090083525]
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Consecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral catalyst, bisox(7)-CuCl2, to form oxazolidinones with remarkable enantioselectivities (94-99% ee) as tert-alkylamine building blocks. The process culminates in a dual-function of the chiral catalyst.
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