Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 87, Pages 10266-10268Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45883k
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Funding
- NSC of the R.O.C. [NSC 101-2113-M-003-001-MY3]
- National Taiwan Normal University [NTNU 100-D-06]
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Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.
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