4.7 Article

Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 84, Pages 9839-9841

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45428b

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Funding

  1. Chinese Academy of Sciences
  2. National Natural Science Foundation of China [21222203, 21172226, 21133011]

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A novel catalytic cross deoxygenative and dehydrogenative coupling reaction of aldehydes and alkenes was established via a cooperative catalysis approach. This transformation provided an efficient and atom-economic protocol for the synthesis of 1,4-skipped dienes from aldehydes and simple alkenes under oxidant-free reaction conditions.

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