Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 79, Pages 9039-9041Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44446e
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Funding
- Research Grants Council of The Hong Kong Special Administration Region [CUHK7/CRF/12G, 403912]
- National Basic Research Program of China (973 Program) [2012CB821600]
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Reaction of [eta(1):eta(5)-(Me2NCH2CH2)C2B9H10]TaMe3 with ArNC at room temperature gave the C-N bond cleavage products, and their type depends upon the aryl group and the amount of ArNC used. A reaction mechanism involving sequential methyl migratory insertion into the C-N multiple bond, followed by an isopropyl carbene insertion into the cage B-H bond, was proposed. All complexes were fully characterized including single-crystal X-ray analyses.
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