Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 78, Pages 8764-8766Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43120g
Keywords
-
Categories
Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Science Foundation of China [21032006, 21172241]
- Shanghai Science and Technology Commission [11ZR1445700]
Ask authors/readers for more resources
Allylic C-H alkylation of allylarenes with dimethyl 2-trifluoromethyl-malonate was successfully developed. The reactions were carried out at room temperature in the presence of a catalytic amount of Pd(OAc)(2)/Ph3P and a stoichiometric amount of 2,6-dimethylbenzoquinone. The reactions avoided defluorination successfully, providing a new method to construct a CF3-containing all-carbon quaternary center.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
