Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 1, Pages 36-38Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36530h
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Funding
- 973 Project from MSTC [2012CB821704]
- NNSFC [20825103, 90922031, 21021061]
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Three heterometallic cluster complexes {Ln(12)Mo(4)} featuring an Ln(12) core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42- anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(III) ions.
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