4.7 Article

A facile avenue to conductive polymer brushes via cyclopentadiene-maleimide Diels-Alder ligation

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 77, Pages 8623-8625

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44683b

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Funding

  1. Alexander von Humboldt Foundation
  2. Karlsruhe Institute of Technology (KIT)
  3. Helmholtz association via its BioInterfaces program
  4. Grant Agency of the Czech Republic
  5. [P205-12-G118]
  6. [P108/12/G108]
  7. [P108/11/1857]

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Cyclopentadienyl end-capped poly(3-hexylthiophene) was employed to fabricate conductive surface tethered polymer brushes via a facile route based on cyclopentadiene-maleimide Diels-Alder ligation. The efficient nature of the Diels-Alder ligation was further combined with a biomimetic polydopamine-assisted functionalization of surfaces, making it an access route of choice for P3HT surface immobilization.

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