4.7 Article

Chiral microporous Ti(salan)-based metal-organic frameworks for asymmetric sulfoxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 64, Pages 7120-7122

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43225d

Keywords

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Funding

  1. NSFC [21025103]
  2. Shanghai Science and Technology Committee [10DJ1400100, 12XD1406300]

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Chiral porous metal-metallosalan frameworks are constructed from an unsymmetrical chiral pyridinecarboxylate ligand derived from Ti(salan) and are shown to be heterogeneous catalysts for asymmetric oxidation of thioethers to sulfoxides.

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