Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 41, Pages 4649-4651Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41663a
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Funding
- Ministerio de Ciencia e Innovacio'n of Spain (MICINN) [CTQ2009-07791]
- Ministerio de Economia y Competitividad (MINECO) [CTQ2012-35790]
- CAM (project AVANCAT) [S2009/PPQ-1634]
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A catalytic highly enantioselective silver-DTBM-segphos catalyzed cycloaddition of alpha-iminoesters with alkylidene azlactones is reported. This procedure provides an effective access to 4-aminopyrrolidine- 2,4-dicarboxylate derivatives with high diastereo- and enantioselectivity.
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