Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 40, Pages 4471-4473Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41357h
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Funding
- European Research Council
- UGC
- U.S. Department of Energy Office of Science laboratory [DE-AC02-06CH11357]
- U.S. National Science Foundation [DMR-1005825]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1005825] Funding Source: National Science Foundation
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We report the mechanical properties of a framework structure, [Cu2F(HF)(HF2)(pyz)(4)][(SbF6)(2)](n) (pyz = pyrazine), in which [Cu(pyz)(2)](2+) layers are pillared by HF2- anions containing the exceptionally strong F-H center dot center dot center dot F hydrogen bonds. Nanoindentation studies on single-crystals clearly demonstrate that such bonds are extremely robust and mechanically comparable with coordination bonds in this system.
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