Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 41, Pages 4667-4669Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42216j
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Funding
- Shanghai Pujiang Program [11PJ1411900]
- East China University of Science & Technology, The Shanghai Committee of Science and Technology [11DZ2260600]
- China 111 Project [B07023]
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We describe an unprecedented Pd(OCOCF3)(2)-catalyzed cascade process for the synthesis of highly functionalized 1,2,3,5-tetra-substituted pyrroles with high efficiency. Unlike documented methods relying on preformed enamines and active halogenated terminal alkenes, the process employs simple 2-alkenal-dicarbonyls and primary amines in 'one-pot'.
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