Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 45, Pages 5156-5158Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41894d
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Funding
- KAKENHI [JSPS/22350059, MEXT/23110711]
- Grants-in-Aid for Scientific Research [22350059] Funding Source: KAKEN
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Biradical 2,2':6',2 ''-terpyridine-6,6 ''-diyl bis(tert-butyl nitroxide) (tpybNO) showed intramolecular ferromagnetic coupling with 2J/k(B) = +2.14(10) K and its complex [Zn(tpybNO)(MeOH)(2)](BF4)(2) exhibited intramolecular antiferromagnetic coupling with 2J/k(B) = -7.5(4) K, suggesting exchange coupling switchable by means of supramolecular chemistry.
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