Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 62, Pages 6965-6967Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44037k
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- Australian Research Council (ARC)
- Australia-India Strategic Research Fund (AISRF)
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The replacement of coordinated acetylacetonate for nitrate around a Dy-III ion results in the enhancement of the single molecule magnet properties of a {(Co2Dy2III)-Dy-III} complex, resulting in a large thermal energy barrier and reduced quantum tunnelling at low temperatures. The analogous Tb-III complex displays field induced SMM behaviour.
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